Calixarenes for Separations by Gregg J. Lumetta, Robin D. Rogers, Aravamudan S. Gopalan

By Gregg J. Lumetta, Robin D. Rogers, Aravamudan S. Gopalan

Content material: Calixarenes for separations / C. David Gutsche -- pt. 1. Calizarene-cation final touch -- Extraction of cesium by means of calix[4]arene-crown-6: from synthesis to procedure / J.-F. Dozol -- improvement of method chemistry for the removing of cesium from acidic nuclear waste by way of calix[4]arene-crown-6 ethers / Peter V. Bonnesen -- Radiation balance of calixarene-based solvent method / R.A. Peterson -- habit of calix[4]arene-bis-crown-6 less than irradiation: electrospray-mass spectrometry research and molecular dynamics simulations on Cs+ and Na+ complexes of a degradation compound / V. Lamare -- Interfacial positive aspects of assisted liquid-liquid extraction of uranyl and cesium salts: a molecular dynamics research / M. Baaden -- Benzyl phenol derivatives: extraction houses of calixarene fragments / Laetitia H. Delmau -- Calixarene-containing extraction mix for the mixed extraction of Cs, Sr, Pu, and Am from alkaline radioactive wastes / Igor V. Smirnov -- Calix[4]arenes with a unique proton-ionizable crew: synthesis and steel ion separations / Richard A. Bartsch -- Separations of sentimental heavy-metal cations by way of reduce rim-functionalized calix[4]arenes / Galina G. Talanova -- CMPO-substituted calixarenes / Volker Böhmer -- Binding of lanthanides(III) and thorium(IV) by means of phosphorylated calixarenes / F. Arnaud-Neu -- Lanthanide calix[4]arene complexes investigated via NMR / B. Lambert -- Bimetallic lanthanide supramolecular edifices with calixarenes / Jean-Claude G. Bünzli -- Molecular popularity via azacalix[3]arenes / Philip D. Hampton -- steel ion complexation and extraction habit of a few acyclic analogs or tert-butyl-calix[4]arene hydroxamate extractants / Timothy N. Lambert -- Calixarenes as ligands in environmentally-benign liquid-liquid extraction media: aqueous biphasic platforms and room tempature ionic beverages / Ann E. Visser -- pt. 2. Calixarene-anion complexation -- Calix[4]pyrrole-functionalized silica gels: novel helps for the HPLC-based separation of anions / Jonathan L. Sessler -- reduce rim amide- and amine-substituted calix[4]arenes as section move extractants for oxyions among an aqueous and an natural part / H. Fred Koch -- pt. three. Calixarene compexation of impartial molecules -- Deep cavities and drugs / Dmitry M. Rudkevich -- Calixarene metalloreceptors: demonstration of measurement and form selectivity inside of a calixarene hollow space / Stephen J. Loeb -- Synthesis and structural research of thiacalixarene derivatives / Mir Wais Hosseini -- Synthesis and fullerene complexation reviews of p-allycalix[5]arenes / Charles G. Gibbs -- Hydrogen-bonded cavities dependent upon resorcin[4]arenes by means of layout / Leonard R. MacGillivray

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J. Inclusion Phenom. Mol. Recognit. Chem. 1996, 23, 305. ; Asfari, Z . ; Vicens, J. J. Inclusion Phenom. Mol. Recognit. Chem. 1997, 27, 169. Asfari, Z . ; Lamare, V . -F. Chem. 1996, 20, 1183. ; Bryan, J. ; Lamare, V . ; Dozol, J. ; Vicens, J. J. , Dalton Trans. 1997, 22, 4191. ; Bohmer, V . ; Reinhoudt, D . ; Schwing, M . - J . ; Wipff, G . New Macrocyclic Extractants for Radioactive Waste Treatment: Ionizable Crown Ethers and Functionalized Calixarenes; Report EUR-17615; European Communities: Luxembourg, 1997.

Adloff, J. Chim. , V o l 61, 1467, 1964. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2000.

The metal ion concentrations in the solvent were determined by multiplying the sum of the metal ion concentrations found in the first and second strip by four. The instrumental detection limit (IDL) for the elements was set equal to three times the standard deviation of a 2% HC1 blank based on 10 replicates. 8 χ 10" . The completeness of the metal ion stripping from the solvent using this method was validated by measuring the sodium distribution by N a tracer in polypropylene vials. The sodium distribution values obtained using the tracer method were only 10-14% higher than the values obtained using ICAP, which, given an experimental uncertainty of ± 5 % in the distribution ratio obtained using either method, is reasonably good agreement.

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