Carbon Dioxide Chemistry. Environmental Issues by J.P. Pradier and C.M. Pradier (Eds.)

By J.P. Pradier and C.M. Pradier (Eds.)

This e-book derives from a workshop held in Sweden to check the environmental implications of the dramatic raise in carbon dioxide degrees within the surroundings within the final 50 years and to discover methods of mitigating greenhouse fuel emissions. This multi-disciplinary process makes it crucial analyzing not just for chemists yet for all engineers, biologists and environmentalists thinking about this crucially vital factor

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1984,140, L239. H. van Tol, A. Gielbert, and B E . Surf. Sci.. 1993, 67, 166. F. Solymosi, A. J. Kocsis, J. Catal. 1980, 65, 428; F. Solymosi and A. Erdohlyi, J. Mol. CataL 1989, 8, 471; F. Solymoi, A. Erdohlyi, and T. Bansagi, XXXXX. 1981, 68, 471. A. Berko and F. Solymosi, Surf. Sci.. 1986, 201, L489; F. Solymosi and A. Berko, J. CataL 1986,101, 458. F. J. Bugyi, J. Chem. Soc. Faradv Trans. I.. 1987, 83, 2015. J. Kiss, X. Revesz, and F. Solymosi, Surf. Sci.. 1988, 207, 36. J. J. Freund, H. Kuhlenbeck, and M.

09, there were very little spectral changes up to 500 K. The loss at 1490 - 1500 cm' was eliminated above 550 - 600 K. At and above K monolayer several K 1 Activation and Reactions of CO2 on Rh 47 Catalysts changes were observed. Annealing the adsorbed layer to 128 K, losses were seen at 780, 890, 1340 and 1620 cm" . At 186 K, the 890 cm" loss was no further detected. The 1340 cm" loss shifted first to 1400 cm" , and above 255 K to 1440 cm" . The initially most intense loss at 1620 cm" underwent only a slight attenuation up to 255 K.

Sci. Technol.. 1982, 20, 592. Activation and Reactions of C 0 on Rh Catalysts 2 F. Solymosi R E A C T I O N KINETICS R E S E A R C H G R O U P O F T H E H U N G A R I A N A C A D E M Y O F SCIENCES, INSTITUTE OF SOLID STATE A N D RADIOCHEMISTRY, ATTILA JOZSEF U N I V E R S I T Y , H-6701 S Z E G E D , P O B O X 168, H U N G A R Y ABSTRACT The activation of C 0 was investigated on K-promoted R h ( l l l ) surface by high resolution electron energy loss spectroscopy. Potassium adatoms greatly increased the binding energy of C 0 and led to the formation of C0 " anion radical characterized by losses at 820, 1360 and 1620 cm" .

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